Rubbing induced reversible fluorescence switching in thiophene-based organic semiconductor films by mechanical amorphisation
نویسندگان
چکیده
Rubbing is applied on thiophene-based organic semiconductor crystalline thin films to induce a reversible mechanical amorphisation. causes fluorescence switching regulated by the polymorphic nature of film. The process thermal annealing.
منابع مشابه
Thiophene-based covalent organic frameworks.
We report the synthesis and characterization of covalent organic frameworks (COFs) incorporating thiophene-based building blocks. We show that these are amenable to reticular synthesis, and that bent ditopic monomers, such as 2,5-thiophenediboronic acid, are defect-prone building blocks that are susceptible to synthetic variations during COF synthesis. The synthesis and characterization of an u...
متن کاملSurface functionalization of organic semiconductor films by segregated monolayers.
Fullerene-based surfactants with semifluoroalkyl chains bearing one of five different functional groups at the end were synthesized and used for the facile surface modification of organic semiconductor films. Surface analysis showed that the modifiers were segregated and the functional groups were exposed at the surface.
متن کاملReversible H-induced switching of the magnetic easy axis in Ni/Cu(001) thin films.
A reversible switching of the easy axis of magnetization for Ni on Cu(001) from in plane to out of plane is found by changing the partial pressure of hydrogen in the gas phase around the sample, allowing even for oscillations of the magnetization direction. A quantitative low-energy electron diffraction study of the diffracted intensity versus electron energy [I(E)] shows that the hydrogen-indu...
متن کاملReversible Mechanical Switching of Magnetic Interactions in a Molecular Shuttle
An acid-base switchable molecular shuttle based on a [2]rotaxane, incorporating stable radical units in both the ring and dumbbell components, is reported. The [2]rotaxane comprises a dibenzo[24]crown-8 ring (DB24C8) interlocked with a dumbbell component that possesses a dialkylammonium (NH2 (+)) and a 4,4'-bipyridinium (BPY(2+)) recognition site. Deprotonation of the rotaxane NH2 (+) centers e...
متن کاملCrystallization in organic semiconductor thin films: a diffuse-interface approach.
The crystallization of organic semiconductor thin films from an amorphous phase often results in a broad range of microstructures and molecular arrangements that in turn critically impact the electronic properties of the film. Here we present a diffuse-interface model of thin film crystallization that accounts for out-of-plane tilting of the kinetically favored crystalline orientation as well a...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Materials Chemistry C
سال: 2021
ISSN: ['2050-7526', '2050-7534']
DOI: https://doi.org/10.1039/d1tc01036k